Providence built its early lead with defense, forcing nine of Villanova's 26 turnovers in the opening eight minutes.
"They had tremendous pressure on us, on the ball and off the ball," Villanova Prep Coach Ray Pierson said. "My hat is off to them, they're a really quick, hard working team and well-coached."
Providence stunned Villanova Prep right out the gate, taking a 12-2 lead six minutes into the game on a steal and pull-up jumper from Katia Dabbaghian, who finished with nine points, seven rebounds and seven steals.
The Wildcats (23-6) started heating up and cut their deficit to four, 12-8, heading into the second quarter behind four points each from Susanna Kolbeck and Natalie Miotti, who both finished with big games.
Kolbeck logged a double-double with game-highs in points (15) and rebounds (14). Miotti added 14 points and seven boards.
Ultimately, Providence (25-5) took too many risks defensively, as Janel Adraneda sat out the entire second quarter and Bea Benedicto (10 points) was on the bench for all but nine seconds of it as both players accumulated three fouls early into the contest.
Bencze dipped deep in his bench as a result and Villanova took advantage, tying the contest at 15, 17 and eventually 21 in the second quarter.
The Wildcats' Emily McAtee squared the score at 21 by nailing a corner jumper eight seconds before the buzzer sounded to end the first half.
"The foul trouble kind of helped [Villanova]," Bencze said. "When you're in foul trouble, you have people who aren't used to being out there for an extended period of time.
"Once we got side tracked and gave them some momentum we couldn't get back into it."